Episode 57: The Mighty Accelguard to the Rescue!

Ash and the gang have arrived in Driftveil City and they decide to go to the Gym. They run into the gym leader where he claims he does not have time to do gym battle and that he has to examine a new vein. They decide to go back to the Pokémon Center until they come across a man named Charles. They go to the Driftveil Market together where the gang receive merchandise for being with Charles. Suddenly a Ducklett starts stealing food from the market and uses Scald on Ash when they give chase. Ducklett meets up with a thief in the car and they take off. Suddenly a character who goes by Mighty Hero Accelguard appears who has come to defeat the thief. He performs an Accelguard kick but lands on the pavement. Accelguard orders Accelgor to intercept them and it uses Double Team. Accelguard uses his motorcycle to catch up to them but runs out of gas.